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Aldrich
2-Iodoxybenzoic acid
661384 -
contains stabilizer, 45 wt. % (IBX)
DOWNLOAD MSDS (PDF)Synonym: SIBX, Stabilized IBX
CAS Number: 61717-82-6
Empirical Formula (Hill Notation): C7H5IO4
Molecular Weight: 280.02
MDL number: MFCD02912492
PubChem Substance ID: 24884529
Properties
| Related Categories | Hypervalent Iodine, Oxidation, Synthetic Reagents |
| contains | stabilizer |
| concentration | 45 wt. % (IBX) |
Description
Application
A stabilized formulation of IBX (SIBX) that displays none of the explosive properties of IBX, while maintaining excellent reactivity and selectivity.1
Reagent used to oxidize Fmoc-protected amino alcohols to the corresponding amino aldehydes in the presence of DMSO.
Stabilized 2-Iodoxybenzoic Acid (SIBX)
Other Notes
The material is stabilized with benzoic acid and isophthalic acid
Packaging
1, 10, 50 g in glass btl
Price and Availability
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Safety Information
| Symbol |   GHS05, GHS07 |
| Signal word | Danger |
| Hazard statements | H314-H335 |
| Precautionary statements | P261-P280-P305 + P351 + P338-P310 |
| Personal Protective Equipment | Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
| Hazard Codes | C |
| Risk Statements | 22-34-44 |
| RIDADR | UN 1759 8/PG 2 |
| WGK Germany | 3 |
Technical information & documentation associated with this product is available in the Safety & Documentation tab.
Articles
Passerini Reaction
The Passerini Reaction is another isonitrile-based MCR that yields a-acyloxy carboxamides in a one-pot synthesis from an aldehyde, isonitrile, and carboxylic acid. Of the three components, the carbon...
Aldrich ChemFiles 2006, 6.7, 3.
Keywords: Passerini reaction
Stabilized 2-Iodoxybenzoic Acid (SIBX)
Since 1994,1 2-iodoxybenzoic acid (IBX) has been well recognized as a very powerful and selective oxidizing agent. Similar to the Dess–Martin periodinane, IBX is an environmentally benign alternative...
Aldrich ChemFiles 2006, 6.2, 14.
Keywords: Dearomatizations, Oxidations
Related Content
References
1. Ozanne, A. et al Org. Lett. 5, 2903, (2003) Abstract
Synth. Commun. 37, 3493, (2007)
Merck 14,5048
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